CA1126201A - Hydrometallurgical method for treating nickel mattes - Google Patents
Hydrometallurgical method for treating nickel mattesInfo
- Publication number
- CA1126201A CA1126201A CA243,609A CA243609A CA1126201A CA 1126201 A CA1126201 A CA 1126201A CA 243609 A CA243609 A CA 243609A CA 1126201 A CA1126201 A CA 1126201A
- Authority
- CA
- Canada
- Prior art keywords
- solution
- process according
- iron
- phase
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 189
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 88
- 238000000034 method Methods 0.000 title claims abstract description 80
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 155
- 229910052742 iron Inorganic materials 0.000 claims abstract description 75
- 230000008569 process Effects 0.000 claims abstract description 69
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000005864 Sulphur Substances 0.000 claims abstract description 41
- 239000000460 chlorine Substances 0.000 claims abstract description 38
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 37
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 24
- 239000007788 liquid Substances 0.000 claims abstract description 17
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000002739 metals Chemical class 0.000 claims abstract description 11
- 230000008030 elimination Effects 0.000 claims abstract description 8
- 238000003379 elimination reaction Methods 0.000 claims abstract description 8
- 230000008929 regeneration Effects 0.000 claims abstract description 8
- 238000011069 regeneration method Methods 0.000 claims abstract description 8
- 150000001805 chlorine compounds Chemical class 0.000 claims abstract description 7
- 238000009854 hydrometallurgy Methods 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 3
- 239000012736 aqueous medium Substances 0.000 claims abstract 2
- 238000007670 refining Methods 0.000 claims abstract 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 43
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 43
- 239000012074 organic phase Substances 0.000 claims description 41
- 239000012071 phase Substances 0.000 claims description 36
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 26
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 15
- 239000000725 suspension Substances 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 239000003085 diluting agent Substances 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- YKGBNAGNNUEZQC-UHFFFAOYSA-N 6-methyl-n,n-bis(6-methylheptyl)heptan-1-amine Chemical compound CC(C)CCCCCN(CCCCCC(C)C)CCCCCC(C)C YKGBNAGNNUEZQC-UHFFFAOYSA-N 0.000 claims description 10
- 239000003456 ion exchange resin Substances 0.000 claims description 8
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 230000001172 regenerating effect Effects 0.000 claims description 7
- 150000005690 diesters Chemical class 0.000 claims description 6
- 235000011007 phosphoric acid Nutrition 0.000 claims description 6
- -1 sulphate ions Chemical class 0.000 claims description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 4
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims description 3
- 229910001626 barium chloride Inorganic materials 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims 6
- 239000007791 liquid phase Substances 0.000 claims 1
- 239000010941 cobalt Substances 0.000 abstract description 20
- 229910017052 cobalt Inorganic materials 0.000 abstract description 20
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 20
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000011084 recovery Methods 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 125
- 238000000605 extraction Methods 0.000 description 37
- 230000009471 action Effects 0.000 description 30
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 27
- 239000011651 chromium Substances 0.000 description 26
- 238000004090 dissolution Methods 0.000 description 26
- 239000008346 aqueous phase Substances 0.000 description 24
- 239000011347 resin Substances 0.000 description 24
- 229920005989 resin Polymers 0.000 description 24
- 238000005868 electrolysis reaction Methods 0.000 description 20
- 239000002904 solvent Substances 0.000 description 19
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 18
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 18
- 238000000746 purification Methods 0.000 description 18
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 15
- 229910052782 aluminium Inorganic materials 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 13
- 239000004411 aluminium Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000005325 percolation Methods 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- 229910052804 chromium Inorganic materials 0.000 description 12
- 239000000706 filtrate Substances 0.000 description 12
- 238000001914 filtration Methods 0.000 description 12
- 238000010828 elution Methods 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 239000012535 impurity Substances 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 8
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 8
- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 229940093635 tributyl phosphate Drugs 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 229910001447 ferric ion Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229910052785 arsenic Inorganic materials 0.000 description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 230000003071 parasitic effect Effects 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 238000010079 rubber tapping Methods 0.000 description 4
- 238000000638 solvent extraction Methods 0.000 description 4
- 235000010269 sulphur dioxide Nutrition 0.000 description 4
- 239000004291 sulphur dioxide Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 3
- 238000000622 liquid--liquid extraction Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JQGGAELIYHNDQS-UHFFFAOYSA-N Nic 12 Natural products CC(C=CC(=O)C)c1ccc2C3C4OC4C5(O)CC=CC(=O)C5(C)C3CCc2c1 JQGGAELIYHNDQS-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- 229960002089 ferrous chloride Drugs 0.000 description 2
- 229910001448 ferrous ion Inorganic materials 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 229910015400 FeC13 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229940035427 chromium oxide Drugs 0.000 description 1
- SDYRVTUTMAXZOC-UHFFFAOYSA-N cobalt;6-methyl-n,n-bis(6-methylheptyl)heptan-1-amine Chemical compound [Co].CC(C)CCCCCN(CCCCCC(C)C)CCCCCC(C)C SDYRVTUTMAXZOC-UHFFFAOYSA-N 0.000 description 1
- 238000000658 coextraction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- HLQQMPGKASWZPH-UHFFFAOYSA-N diethyl hexyl phosphate Chemical compound CCCCCCOP(=O)(OCC)OCC HLQQMPGKASWZPH-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- XEEYBQQBJWHFJM-IGMARMGPSA-N iron-56 Chemical compound [56Fe] XEEYBQQBJWHFJM-IGMARMGPSA-N 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000009868 nickel metallurgy Methods 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- YJBMMHPCGWCCOH-UHFFFAOYSA-N octan-3-yl dihydrogen phosphate Chemical class CCCCCC(CC)OP(O)(O)=O YJBMMHPCGWCCOH-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 231100000925 very toxic Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0423—Halogenated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
- C22B3/282—Aliphatic amines
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Inorganic Fibers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000387835A CA1142130A (en) | 1975-01-16 | 1981-10-13 | Hydrometallurgical method for treating nickel mattes |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR75-01264 | 1975-01-16 | ||
| FR7501264A FR2297925A1 (fr) | 1975-01-16 | 1975-01-16 | Procede hydrometallurgique pour le traitement de mattes de nickel |
| FR7538166A FR2334756A2 (fr) | 1975-12-12 | 1975-12-12 | Procede hydrometallurgique pour le traitement de mattes de nickel |
| FR75-38166 | 1975-12-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1126201A true CA1126201A (en) | 1982-06-22 |
Family
ID=26218692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA243,609A Expired CA1126201A (en) | 1975-01-16 | 1976-01-15 | Hydrometallurgical method for treating nickel mattes |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4236981A (en]) |
| JP (1) | JPS6018733B2 (en]) |
| AR (1) | AR205314A1 (en]) |
| AU (1) | AU499399B2 (en]) |
| BR (1) | BR7600227A (en]) |
| CA (1) | CA1126201A (en]) |
| ES (1) | ES444363A1 (en]) |
| FI (1) | FI65813C (en]) |
| GB (1) | GB1484121A (en]) |
| GR (1) | GR58526B (en]) |
| IT (1) | IT1056580B (en]) |
| LU (1) | LU74185A1 (en]) |
| NL (1) | NL188296C (en]) |
| NO (1) | NO146993C (en]) |
| PT (1) | PT64703B (en]) |
| SE (2) | SE458204B (en]) |
| YU (1) | YU13276A (en]) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107385233A (zh) * | 2017-07-07 | 2017-11-24 | 金川集团股份有限公司 | 一种高铁低镍锍氯化精炼的方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2373610A1 (fr) | 1976-12-09 | 1978-07-07 | Minemet Rech Sa | Procede pour la mise en solution des metaux non-ferreux contenus dans des minerais et autres composes oxygenes |
| US4384940A (en) * | 1982-01-21 | 1983-05-24 | Inco Limited | Chlorine leaching of nickel-cobalt-iron sulphides |
| US4956154A (en) * | 1988-03-09 | 1990-09-11 | Unc Reclamation | Selective removal of chromium, nickel, cobalt, copper and lead cations from aqueous effluent solutions |
| CN104099637A (zh) * | 2013-04-07 | 2014-10-15 | 中国科学院过程工程研究所 | 一种镍阳极电解液中杂质金属离子的逐步深度去除方法 |
| PL404172A1 (pl) * | 2013-05-31 | 2014-12-08 | Centrum Metal Odczynniki Chemiczne-Midas Investment Spółka Z Ograniczoną Odpowiedzialnością Spółka Komandytowa | Otrzymywanie roztworów azotanu(V) niklu(II) z odpadowych roztworów niklowych zawierających siarczany i/lub chlorki |
| JP6418140B2 (ja) * | 2015-11-27 | 2018-11-07 | 住友金属鉱山株式会社 | ニッケルの製錬方法、塩素浸出方法 |
| CN115058597B (zh) * | 2022-06-30 | 2024-06-04 | 盛隆资源再生（无锡）有限公司 | 一种含钙、铁、钴、镍的电镀污泥的回收处理方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2277895A1 (fr) * | 1974-07-10 | 1976-02-06 | Nickel Le | Procede pour la production de valeurs metalliques a partir de ferro-nickel |
| CA1064856A (en) * | 1975-02-12 | 1979-10-23 | Alexander Illis | Purification of nickel electrolyte by electrolytic oxidation |
-
1976
- 1976-01-01 AR AR26194776A patent/AR205314A1/es active
- 1976-01-13 AU AU10232/76A patent/AU499399B2/en not_active Expired
- 1976-01-13 GR GR49762A patent/GR58526B/el unknown
- 1976-01-13 SE SE7600283A patent/SE458204B/xx not_active IP Right Cessation
- 1976-01-14 LU LU74185A patent/LU74185A1/xx unknown
- 1976-01-14 FI FI760071A patent/FI65813C/fi not_active IP Right Cessation
- 1976-01-15 GB GB165776A patent/GB1484121A/en not_active Expired
- 1976-01-15 NO NO760138A patent/NO146993C/no unknown
- 1976-01-15 PT PT6470376A patent/PT64703B/pt unknown
- 1976-01-15 BR BR7600227A patent/BR7600227A/pt unknown
- 1976-01-15 CA CA243,609A patent/CA1126201A/en not_active Expired
- 1976-01-16 ES ES76444363A patent/ES444363A1/es not_active Expired
- 1976-01-16 NL NL7600461A patent/NL188296C/xx not_active IP Right Cessation
- 1976-01-16 JP JP51004563A patent/JPS6018733B2/ja not_active Expired
- 1976-01-16 IT IT1241876A patent/IT1056580B/it active
- 1976-01-16 YU YU13276A patent/YU13276A/xx unknown
-
1979
- 1979-07-05 US US06/054,888 patent/US4236981A/en not_active Expired - Lifetime
-
1980
- 1980-12-11 SE SE8008714A patent/SE446747B/sv not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107385233A (zh) * | 2017-07-07 | 2017-11-24 | 金川集团股份有限公司 | 一种高铁低镍锍氯化精炼的方法 |
| CN107385233B (zh) * | 2017-07-07 | 2019-05-10 | 金川集团股份有限公司 | 一种高铁低镍锍氯化精炼的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU499399B2 (en) | 1979-04-12 |
| NO760138L (en]) | 1976-07-19 |
| GB1484121A (en) | 1977-08-24 |
| NL188296B (nl) | 1991-12-16 |
| BR7600227A (pt) | 1976-08-31 |
| NO146993B (no) | 1982-10-04 |
| JPS6018733B2 (ja) | 1985-05-11 |
| AU1023276A (en) | 1977-07-21 |
| NL188296C (nl) | 1992-05-18 |
| IT1056580B (it) | 1982-02-20 |
| SE7600283L (sv) | 1976-07-19 |
| JPS5198622A (en]) | 1976-08-31 |
| FI65813B (fi) | 1984-03-30 |
| SE458204B (sv) | 1989-03-06 |
| ES444363A1 (es) | 1977-10-01 |
| GR58526B (en) | 1977-10-31 |
| FI65813C (fi) | 1984-07-10 |
| PT64703B (fr) | 1977-08-10 |
| NO146993C (no) | 1983-01-12 |
| LU74185A1 (en]) | 1977-07-22 |
| SE8008714L (sv) | 1980-12-11 |
| FI760071A7 (en]) | 1976-07-17 |
| SE446747B (sv) | 1986-10-06 |
| DE2601534A1 (de) | 1976-12-02 |
| US4236981A (en) | 1980-12-02 |
| YU13276A (en) | 1982-06-30 |
| DE2601534B2 (de) | 1977-03-17 |
| NL7600461A (nl) | 1976-07-20 |
| AR205314A1 (es) | 1976-04-21 |
| PT64703A (fr) | 1976-02-01 |
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